The “Gossip Girl” gal joined up with her "The Roommate" co-star Minka Kelly as the gals made their way down the red carpet before heading inside the Nokia Theatre for the exciting show.
During the course of the festivities, Leighton and Minka took the stage alongside one another to introduce performer Kid rock to the audience.
In related news, it was recently announced that Ms Meester is set to present an award at the annual Golden Globes coming up on January 16.
